Exhibit 99.4
FORM OF LETTER TO CLIENTS OF BROKERS AND OTHER NOMINEE HOLDERS
SYNALLOY CORPORATION
Subscription Rights to Purchase Shares of Common Stock
Offered Pursuant to Subscription Rights
Distributed to Stockholders
of Synalloy Corporation
November 30, 2021
To Our Clients:
Enclosed for your consideration are a prospectus supplement dated
November 30, 2021 (the “Prospectus Supplement” and together with the base prospectus dated April 19, 2019, the “Prospectus”) and the “Instructions as to Use of Synalloy Corporation Non-Transferable Subscription Rights
Certificates” relating to the rights offering (the “Rights Offering”) by Synalloy Corporation, a Delaware corporation (the “Company”), of shares of its common stock, par value $1.00 per share (the “Common Stock”), pursuant to
non-transferable subscription rights (“Subscription Rights”) distributed to all stockholders of record of the Company as of 5:00 p.m., Eastern Time, on November 29, 2021 (the “Record Date”). The Subscription Rights and Common Stock
are described in the Prospectus Supplement.
In the Rights Offering, we are distributing at no charge to the
holders of our Common Stock on the Record Date, non-transferable Subscription Rights to purchase up to an aggregate of 785,103 shares of our Common Stock, as described in the Prospectus Supplement.
The Subscription Rights will expire if not exercised prior to 5:00
p.m., Eastern Time, on December 16, 2021 (the “Expiration Date”).
As described in the Prospectus Supplement, you will receive one
Subscription Right for each share of Common Stock owned as of 5:00 p.m., Eastern Time, on the Record Date. Each Basic Subscription Right will entitle you to subscribe for 0.083768 shares of Common Stock (the “Basic Subscription Right”) at
the subscription price of $12.75 per whole share (the “Subscription Price”). For example, if you owned 1,000 shares of Common Stock as of 5:00 p.m., Eastern Time, on the Record Date, you would be granted Subscription Rights to purchase an
aggregate of 83 shares of Common Stock (rounded down to the nearest whole share, with the total subscription payment being adjusted accordingly, as discussed below) at the Subscription Price per share. After the completion of the Rights Offering,
any excess subscription amounts paid by a subscriber will be returned to the subscriber, without interest or deduction, as soon as practicable.
In the event that you purchase all of the shares of Common Stock
available to you pursuant to your Basic Subscription Right, you may also exercise an over-subscription right (the “Oversubscription Privilege”) to purchase a portion of any shares of Common Stock that are not purchased by stockholders
through the exercise of their Basic Subscription Rights (the “Unsubscribed Shares”), subject to the availability and pro rata allocation of the Unsubscribed Shares among all persons exercising their Oversubscription Privilege. To the
extent the Unsubscribed Shares are not sufficient to satisfy all proper exercises of the Oversubscription Privilege, then the Unsubscribed Shares will be prorated among those who properly exercised the Oversubscription Privilege based on the
number of shares each person subscribed for under the Basic Subscription Right. If this pro rata allocation results in any person receiving a greater number of Unsubscribed Shares than the person subscribed for pursuant to the exercise of the
Oversubscription Privilege, then such person will be allocated only that number of Unsubscribed Shares for which the person oversubscribed, and the remaining Unsubscribed Shares will be allocated among all other persons exercising the
Oversubscription Privilege on the same pro rata basis described above. The proration process will be repeated until all Unsubscribed Shares have been allocated or all exercises of the Oversubscription Privilege have been fulfilled, whichever
occurs earlier.